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1

Studies towards the total synthesis of rapamycin: Preparation of the cyclohexyl C33C42 fragment and further coupling to afford the C22C42 carbon unit

Cyrille Kouklovsky, Steven V. Ley, Stephen P. Marsden

Journal:

Tetrahedron Letters

Year:

1994

Language:

english

File:

PDF, 288 KB

english, 1994

2

Bioinspired Oxidative Cyclization of the Geissoschizine Skeleton for the Total Synthesis of (-)-17-nor-Excelsinidine

Jarret, Maxime, Tap, Aurélien, Kouklovsky, Cyrille, Poupon, Erwan, Evanno, Laurent, Vincent, Guillaume

Journal:

Angewandte Chemie International Edition

Year:

2018

Language:

english

File:

PDF, 1.74 MB

english, 2018

3

Bioinspired Oxidative Cyclization of the Geissoschizine Skeleton for the Total Synthesis of (-)-17-nor-Excelsinidine

Jarret, Maxime, Tap, Aurélien, Kouklovsky, Cyrille, Poupon, Erwan, Evanno, Laurent, Vincent, Guillaume

Journal:

Angewandte Chemie

Year:

2018

Language:

english

File:

PDF, 1.74 MB

english, 2018

4

Bioinspired Oxidative Cyclization of the Geissoschizine Skeleton for the Enantioselective Total Synthesis of Mavacuran Alkaloids

Jarret, Maxime, Tap, Aurélien, Turpin, Victor, Gallard, Jean-François, Kouklovsky, Cyrille, Poupon, Erwan, Vincent, Guillaume, Evanno, Laurent

Journal:

Angewandte Chemie

Year:

2019

Language:

english

File:

PDF, 1.59 MB

english, 2019

5

Bioinspired Divergent Oxidative Cyclization from Strictosidine and Vincoside Derivatives: Second Generation Total Synthesis of Cymoside and Access to an Original HexacyclicâFused Furo[3,2âb]indoline

Dou, Yingchao, Kouklovsky, Cyrille, Vincent, Guillaume

Journal:

Chemistry (Weinheim an der Bergstrasse, Germany)

Year:

2020

File:

PDF, 1.66 MB

2020

6

Oxazoline N-Oxide Mediated [3+2] Cycloadditions: Application to a Formal Synthesis of a (+)-β-Methylcarbapenem

Marc Mauduit, Cyrille Kouklovsky, Yves Langlois

Journal:

European Journal of Organic Chemistry

Year:

2000

Language:

english

File:

PDF, 350 KB

english, 2000

7

Oxazoline N-Oxide-Mediated [2+3] Cycloadditions: New Access to Quaternary Asymmetric Centres

Stéphane Collon, Cyrille Kouklovsky, Yves Langlois

Journal:

European Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 138 KB

english, 2002

8

Stereodivergent Synthesis of Substituted N,O-Containing Bicyclic Compounds by Sequential Addition of Nucleophiles to N-Alkoxybicyclolactams

Dr. Guillaume Vincent, Dr. Régis Guillot, Prof. Dr. Cyrille Kouklovsky

Journal:

Angewandte Chemie

Year:

2011

Language:

english

File:

PDF, 322 KB

english, 2011

9

Stereodivergent Synthesis of Substituted N,O-Containing Bicyclic Compounds by Sequential Addition of Nucleophiles to N-Alkoxybicyclolactams

Dr. Guillaume Vincent, Dr. Régis Guillot, Prof. Dr. Cyrille Kouklovsky

Journal:

Angewandte Chemie International Edition

Year:

2011

Language:

english

File:

PDF, 311 KB

english, 2011

10

Total Synthesis of Rapamycin

Steven V. Ley, Miles N. Tackett, Matthew L. Maddess, James C. Anderson, Paul E. Brennan, Michael W. Cappi, Jag P. Heer, Céline Helgen, Masakuni Kori, Cyrille Kouklovsky, Stephen P. Marsden, Joanne Nor

Journal:

Chemistry - A European Journal

Year:

2009

Language:

english

File:

PDF, 955 KB

english, 2009

11

Ring-Rearrangement Metathesis of Nitroso Diels–Alder Cycloadducts

Dr. Guillaume Vincent , Prof. Cyrille Kouklovsky

Journal:

Chemistry - A European Journal

Year:

2011

Language:

english

File:

PDF, 344 KB

english, 2011

12

ChemInform Abstract: New Uses of Oxazolines, Oxazoline N-Oxides and Dioxolanyliums in Asymmetric Synthesis

Y. LANGLOIS, A. POUILHES, C. KOUKLOVSKY, J.-F. MORELLI, A. HAUDRECHY, M. KOBAYAKAWA, C. ANDRE-BARRES, T. BERRANGER, O. DIRAT

Journal:

Year:

1997

File:

PDF, 25 KB

1997

13

ChemInform Abstract: Cyanomethylene Cyclopropane, a Useful Dipolarophile and Dienophile in [2 + 3] and [2 + 4] Cycloadditions.

M. MAUDUIT, C. KOUKLOVSKY, Y. LANGLOIS

Journal:

Year:

1998

File:

PDF, 33 KB

1998

14

ChemInform Abstract: Oxazoline N-Oxide-Mediated [2 + 3] Cycloadditions: Application to a Total Synthesis of the Hypocholesterolemic Agent 1233A.

O. DIRAT, C. KOUKLOVSKY, Y. LANGLOIS

Journal:

Year:

1999

File:

PDF, 33 KB

1999

15

ChemInform Abstract: Oxazoline N-Oxide-Mediated [2 + 3] Cycloadditions. Application to a Synthesis of (-)-Tetrahydrolipstatin.

O. Dirat, C. Kouklovsky, Yves Langlois

Journal:

Year:

1999

File:

PDF, 30 KB

1999

16

ChemInform Abstract: Oxazoline N-Oxide Mediated [2 + 3] Cycloadditions. Application to a Formal Synthesis of (+)-Carpetimycin A.

M. Mauduit, C. Kouklovsky, Y. Langlois, C. Riche

Journal:

Year:

2000

File:

PDF, 31 KB

2000

17

ChemInform Abstract: Oxazoline N-Oxide Mediated Asymmetric Cycloadditions: Recent Progress in the Stereoselective Syntheses of β-Lactones and β-Lactams

O. Dirat, C. Kouklovsky, M. Mauduit, Y. Langlois

Journal:

Year:

2001

File:

PDF, 28 KB

2001

18

[2 + 3] Cycloadditions Between Nitroalkenes and Camphor-Derived Oxazoline N-Oxides and Radical Denitration of the Adducts.

Arnaud Voituriez, Julien Moulinas, Cyrille Kouklovsky, Yves Langlois

Journal:

Year:

2003

File:

PDF, 154 KB

2003

19

Lewis Acid Promoted Hetero Diels—Alder Cycloaddition of α-Acetoxynitroso Dienophiles.

Geraldine Calvet, Marion Dussaussois, Nicolas Blanchard, Cyrille Kouklovsky

Journal:

Year:

2004

File:

PDF, 24 KB

2004

20

One or More CC Bond(s) Formed by Substitution: Substitution of Carbon—Nitrogen, —Phosphorus, —Arsenic, —Antimony, —Boron, —Silicon, —Germanium, and —Metal Functions

Journal:

Year:

2005

File:

PDF, 8 KB

2005

21

ChemInform Abstract: Amino Acid Homologation by the Blaise Reaction: A New Entry into Nitrogen Heterocycles.

Cam Thuy Hoang, Francelin Bouillere, Sine Johannesen, Anais Zulauf, Cecilia Panel, Annie Pouilhes, Didier Gori, Valerie Alezra, Cyrille Kouklovsky

Journal:

Year:

2009

Language:

english

File:

PDF, 42 KB

english, 2009

22

ChemInform Abstract: Camphor Derivatives in Asymmetric Cycloadditions and Rearrangements

Yves Langlois, Cyrille Kouklovsky

Journal:

Year:

2010

File:

PDF, 15 KB

2010

23

ChemInform Abstract: Synthetic Approaches to Racemic Porantheridine (VI) and 8-Epihalosaline (VII) via a Nitroso Diels—Alder Cycloaddition/Ring-Rearrangement Metathesis Sequence.

Pierre Sancibrao, Delphine Karila, Cyrille Kouklovsky, Guillaume Vincent

Journal:

Year:

2010

File:

PDF, 31 KB

2010

24

ChemInform Abstract: Stereodivergent Synthesis of Substituted N,O-Containing Bicyclic Compounds by Sequential Addition of Nucleophiles to N-Alkoxybicyclolactams.

Guillaume Vincent, Regis Guillot, Cyrille Kouklovsky

Journal:

Year:

2011

File:

PDF, 46 KB

2011

25

ChemInform Abstract: Ring-Rearrangement Metathesis of Nitroso Diels—Alder Cycloadducts.

Guillaume Vincent, Cyrille Kouklovsky

Journal:

Year:

2011

File:

PDF, 29 KB

2011

26

ChemInform Abstract: Foldamers Containing γ-Amino Acid Residues or Their Analogues: Structural Features and Applications

Francelin Bouillere, Sophie Thetiot-Laurent, Cyrille Kouklovsky, Valerie Alezra

Journal:

Year:

2012

File:

PDF, 19 KB

2012

27

Synthesis and biological evaluation of bengacarboline derivatives

Annie Pouilhès, Cyrille Kouklovsky, Yves Langlois, Jean-Pierre Baltaze, Stéphane Vispé, Jean-Philippe Annereau, Jean-Marc Barret, Anna Kruczynski, Christian Bailly

Journal:

Bioorganic & Medicinal Chemistry Letters

Year:

2008

Language:

english

File:

PDF, 303 KB

english, 2008

28

Accurate conformation analysis in solution: NMR and DFT/PCM study of the S-3-(1-naphthoyl)-4-isopropyl-2,2-dimethyloxazolidin-5-one in CDCl3

Mathieu Branca, Valérie Alezra, Cyrille Kouklovsky, Pierre Archirel

Journal:

Year:

2008

Language:

english

File:

PDF, 381 KB

english, 2008

29

α-Acyloxynitroso dienophiles in [4+2] hetero Diels–Alder cycloadditions: mechanistic insights

Géraldine Calvet, Susannah C. Coote, Nicolas Blanchard, Cyrille Kouklovsky

Journal:

Year:

2010

Language:

english

File:

PDF, 991 KB

english, 2010

30

New chiral amino acid-derived α-acyloxynitroso reagents for asymmetric nitroso Diels–Alder reactions

Hailing Li, Didier Gori, Cyrille Kouklovsky, Guillaume Vincent

Journal:

Tetrahedron: Asymmetry

Year:

2010

Language:

english

File:

PDF, 404 KB

english, 2010

31

Camphor-derived sulfonylhydrazines: catalysts for Diels–Alder cycloadditions

Yves Langlois, Alain Petit, Pauline Rémy, Marie-Christine Scherrmann, Cyrille Kouklovsky

Journal:

Tetrahedron Letters

Year:

2008

Language:

english

File:

PDF, 187 KB

english, 2008

32

Towards the synthesis of the C37-C42 fragment of rapamycin: intramolecular reactions of allyl silanes with oxonium ions generated from α-alkoxy sulfones.

Steven V. Ley, Cyrille Kouklovsky

Journal:

Year:

1994

Language:

english

File:

PDF, 1005 KB

english, 1994

33

α,β-Unsaturated oxazolines and oxazine, useful dienophiles in the Diels-Alder reaction

Annie Pouilhès, Cyrille Kouklovsky, Nicole Langlois, Yves Langlois

Journal:

Tetrahedron Letters

Year:

1987

Language:

english

File:

PDF, 166 KB

english, 1987

34

Chiral α,β-unsaturated oxazolines in the asymmetric diels-alder reaction

A. Pouilhes, E. Uriarte, C. Kouklovsky, N. Langlois, Y. Langlois, A. Chiaroni, C. Riche

Journal:

Tetrahedron Letters

Year:

1989

Language:

english

File:

PDF, 226 KB

english, 1989

35

Cyanomethylene cyclopropane, a useful dipolarophile and dienophile in [2+3] and [2+4] cycloadditions

Marc Mauduit, Cyrille Kouklovsky, Yves Langlois

Journal:

Tetrahedron Letters

Year:

1998

Language:

english

File:

PDF, 214 KB

english, 1998

36

Double diastereoselection in asymmetric [2+3] cycloaddition of chiral oxazoline N-oxides: application to the kinetic resolution of a racemic α,β-unsaturated δ-lactone

Olivier Dirat, Cyrille Kouklovsky, Yves Langlois, Philippe Lesot *, Jacques Courtieu

Journal:

Tetrahedron: Asymmetry

Year:

1999

Language:

english

File:

PDF, 231 KB

english, 1999

37

Foldamers containing γ-amino acid residues or their analogues: structural features and applications

Francelin Bouillère, Sophie Thétiot-Laurent, Cyrille Kouklovsky, Valérie Alezra

Journal:

Year:

2011

Language:

english

File:

PDF, 1.25 MB

english, 2011

38

Intermolecular nitroso Diels–Alder cycloaddition of α-acetoxynitroso derivatives in aqueous medium

Calvet, Géraldine, Guillot, Régis, Blanchard, Nicolas, Kouklovsky, Cyrille

Journal:

Organic & Biomolecular Chemistry

Year:

2005

Language:

english

File:

PDF, 218 KB

english, 2005

39

Absolute Asymmetric Synthesis of Tertiary α-Amino Acids

Thi Thoa Mai, Dr. Mathieu Branca, Didier Gori, Dr. Régis Guillot, Prof. Cyrille Kouklovsky, Dr. Valérie Alezra

Journal:

Angewandte Chemie

Year:

2012

Language:

english

File:

PDF, 584 KB

english, 2012

40

Absolute Asymmetric Synthesis of Tertiary α-Amino Acids

Thi Thoa Mai, Dr. Mathieu Branca, Didier Gori, Dr. Régis Guillot, Prof. Cyrille Kouklovsky, Dr. Valérie Alezra

Journal:

Angewandte Chemie International Edition

Year:

2012

Language:

english

File:

PDF, 771 KB

english, 2012

41

Enantioselective Intramolecular Hydroamination of Secondary Amines Catalyzed by Easily Accessible Ate and Neutral Rare-Earth Complexes

Dr. Clémence Queffelec, Dr. Fabien Boeda, Dr. Annie Pouilhès, Dr. Abdelkrim Meddour, Prof. Cyrille Kouklovsky, Dr. Jérôme Hannedouche, Dr. Jacqueline Collin, Dr. Emmanuelle Schulz

Journal:

Year:

2011

Language:

english

File:

PDF, 216 KB

english, 2011

42

ChemInform Abstract: Alkyl Metals

S. V. LEY, C. KOUKLOVSKY

Journal:

Year:

1996

File:

PDF, 24 KB

1996

43

Synthesis of Ferrocenyl Schiff Bases Under Solvent-Free Conditions Using Microwave Irradiation

Öztürk, Gülşen, Petit, Alain, Kouklovsky, Cyrille

Journal:

Synthetic Communications

Year:

2008

Language:

english

File:

PDF, 152 KB

english, 2008

44

ChemInform Abstract: Absolute Asymmetric Synthesis of Tertiary α-Amino Acids.

Thi Thoa Mai, Mathieu Branca, Didier Gori, Regis Guillot, Cyrille Kouklovsky, Valerie Alezra

Journal:

Year:

2012

File:

PDF, 36 KB

2012

45

.alpha.,.beta.-Unsaturated oxazolines, a powerful tool in asymmetric Diels-Alder cycloadditions

Kouklovsky, Cyrille, Pouilhes, Annie, Langlois, Yves

Journal:

Journal of the American Chemical Society

Year:

1990

Language:

english

File:

PDF, 1.13 MB

english, 1990

46

Memory of Chirality of Tertiary Aromatic Amide: Application to the Asymmetric Synthesis of ( S )-α-MethylDOPA

Mai, Thi Thoa, Viswambharan, Baby, Gori, Didier, Kouklovsky, Cyrille, Alezra, Valérie

Journal:

Journal of Organic Chemistry

Year:

2012

Language:

english

File:

PDF, 492 KB

english, 2012

47

Original β,γ-diamino acid as an inducer of a γ-turn mimic in short peptides

Thétiot-Laurent, Sophie, Bouillère, Francelin, Baltaze, Jean-Pierre, Brisset, François, Feytens, Debby, Kouklovsky, Cyrille, Miclet, Emeric, Alezra, Valérie

Journal:

Organic & Biomolecular Chemistry

Year:

2012

Language:

english

File:

PDF, 1.14 MB

english, 2012

48

A Stereoselective Entry into Functionalized 1,2-Diamines by Zinc-Mediated Homologation of α-Aminoacids

Hoang, Cam Thuy, Alezra, Valérie, Guillot, Régis, Kouklovsky, Cyrille

Journal:

Organic Letters

Year:

2007

Language:

english

File:

PDF, 118 KB

english, 2007

49

Comprehensive Chirality || 3.16 Synthetically Derived Auxiliaries: Amines (including Diamines), Hydrazines and Hydroxylamines, and Amino Alcohols

Year:

2012

Language:

english

File:

PDF, 4.47 MB

english, 2012

50

FeCl 3 -Mediated Friedel-Crafts Hydroarylation with Electrophilic N -Acetyl Indoles for the Synthesis of Benzofuroindolines

Beaud, Rodolphe, Guillot, Régis, Kouklovsky, Cyrille, Vincent, Guillaume

Journal:

Angewandte Chemie

Year:

2012

Language:

english

File:

PDF, 473 KB

english, 2012

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